The point in your argument I don't follow is, you say the physical brain is the "substrate" for the emergent property of consciousness, but then continue to say that the brain is not equivalent to the consciousness. Is your point akin to saying the brain is the hardware, but the software is making use of the hardware, but we don't know what the software is? Or are you saying there is an outside element that creates the freewill?
Sorry, if I said brain, I meant body. Or I guess then we might just get into a discussion on what we mean by brain? My point was that life-forms that don't have brains as we have them still show signs of consciousness, and to me, that seems to be more of a problem for you than me. And as for the software comparison, I think the better analogy for me might that consciousness writes the software that operates on the hardware. Software comes "preloaded," but we do have the ability to modify and alter.
For the sake of scientific inquiry, shouldn't the assumption be the lack of anything additional to the physical brain? The brain is very complex, and nobody can with a straight face say that, from a complexity point of view, the brain couldn't give rise to something like that. The brain has trillions of interconnected synapses, that is far more than the rather simplistic human choice process would need.
But the assumption that the brain is what creates consciousness runs into problems with eukaryote's (my biology is very rusty, so that may be the wrong term), so I'd say it's an inappropriate use of Occam's Razor . Also, considering we don't have a real test for someone else being conscious, we still all have ourselves as indication that there is something additional to the simple physical brain. I'm not sure it's really physical possible to prove consciousness, at least if you do, you'll finally have an irrefutable answer to solipsism. As for as it being possibly true, I think it is still possible that you're right. In terms of scientific inquiry, I think it's valid to investigate this possibility. However, I do not think it's a solid fact as of yet, and I don't think it's write to default to determinism
So, neurons firing requires the movement, freeing, and flow of electrons; but the escape of an electron, on an individual basis, isn't strictly deterministic. Neuroscience can point to neurons firing as good indications of what happens, but they can't really give a physically appropriate reasons for why that Neuron fires, becuase that explanation runs face into quantum mechanics. Our conscious awareness seems to play a role in our daily experiences, and over what neurons are firing in the brain; and given what we know about quantum mechanics, is it not at least possible that self-consciousness is responsible for the occasional firing of some neurons? Like above, I'm not really saying this
is true, simply that what we know now leaves open the possibilities of something akin to this.
Or perhaps it is just random, we're on for the ride, and there is no determined future. We'd then be both not free, and not determined.