The only order change that would make sense in I&W would be to have Metropolis as the opener. Playing it in reverse would be a terrible flow, to start up with Learning to Live and then have Wait for Sleep is just.... no.
Slightly off-topic, Metallica did that twice. They played the black album in reverse, and it made somehow sense to have the biggest hits like Sad But True and Enter Sandman at the end, but they played also Ride the Lightning in reverse, which was very weird 'cause Fight Fire with Fire is the perfect opener and The Call of Ktulu is the perfect closer.